Hilliard Emission Controls, Inc.
3100 Edloe Street Suite 350
Houston, TX 77027
888-621-3132
.
PURGIT emission controls

PURGIT has vapor control & recovery equipment for tanks and pipelines.

Combustion by-products from flares and combustors range from unburned VOC to CO2, CO and NOx (greenhouse gases) to hazardous by-products which have to be scrubbed. Activated carbon is problematic and expensive to operate. In comparison, a vapor condenser can handle chlorinated solvents and hydrocarbons better than any other control device because it does not make any NOx or CO. In fact it does not have an exhaust stack. The side benefit is that it recovers cargo that can be recycled.

PURGIT has been in the tank vapor control business since 1993. We chose to develop a refrigerated 'closed loop' system because of the operational and environmental benefits. It can actually handle the maximum flow rate when the tank vapor is concentrated. We claim and can prove 650 scfm from the 1st minute of operation and we do it all the time. Did you know that the vapor space in a gasoline storage tank may measure 50% by volume concentration? That is the same that you might find in the gasoline tank on your car in the summer. That is very rich, so rich it will not burn without diluting with air. Diluting the tank with air will create an explosive mixture in the storage tank. PURGIT does not dilute your tank with air. We are the only company that can process the rich vapors without adding air. We can process zero air vapors.


H Hilliard 4/00
The first vapor condenser C-1 with
 a crude oil tank in the background.
Started condenser service in 1999

New condenser 3/1/07
Unit C-2 built 12/06
Placed in service 3/07 Recovered over 80 tons VOC
liquid in just 16 months!

EDC from tank barge
Unit C-2 recovered this ethylene dichloride
 from one tank in about 8 hours in Dec 07
It is suitable for recycling.

1,500 gallons of VOC 4/08
Gasoline type VOC condensate
recovered by PURGIT condenser C-2
April 2008 final recovery over 2,000 gallons

Isoprene tank 2/08
100,000 barrel cap. storage tank - isoprene
Final recovery 5,500 gallons. Recovered and transfered
to adjoining pipeline segment. Feb 2008 by PURGIT C-2

Butane pipe line job 3/08
Butane pipeline site near Chicago
Recovered and pumped to tanker
over 1,100 gallons of butane March 2008
PURGIT unit C-2


VIDEO of case history gasoline job, 2007:

The customer had a gasoline tank that needed to be cleaned. PURGIT was called to do the vapor control. The tank is 86' diameter x 38' high and it has a cone roof. The tank has over 1psi of pressure from a nitrogen pad system.
This is actual footage on site during the vapor control.

Video A shows the setup at the start of the job. We planned to transfer the condensate into drums. However we were recovering at the rate of 2 drums per hour and the drums quickly became impractical. This video starts out showing the condensate in the sight glass, then it pans to the actual tank we are working on. The video then pans back to the drums and then to the PURGIT condenser. The next day we changed over to the frac tank.
Same video, different formats:  PurgitVideoA.3g2 (2.8 meg) , 
PurgitVideoA.mov (5 meg) ,  PurgitVideoA.avi (7.5 meg) , PurgitVideoA.mpg (9.7 meg)

Video B shows the condensate as it is transfered to the frac tank. We finally recovered about 1,200 gallons.
We were recovering so much condensate that we a manifold to collect from the purgit condenser pumps. This video shows the manifold and the frac tank and then pans to the PURGIT condenser. We processed 4 tank volumes, that was about 883,000 cubic feet of vapor. This condensing was completed in about 22 hours, it consumed about 25,000 pounds of liquid nitrogen. The system recovered about 1,200 gallons of gasoline which was put in the frac tank. We maintained the pressure on the tank to prevent the tank from going into a partial pressure condition with the removal of the gasoline vapor.

Same video, different formats: PurgitVideoB.3g2 (1.4meg) ,  PurgitVideoB.mov (3.2 meg) ,  PurgitVideoB.avi (3.8 meg) ,  PurgitVideoB.mpg (5 meg)


Gasoline - VOC cargo
Photographs taken during the vapor control phase when cleaning a gasoline tank with a vapor condenser. This refrigerated, low temperature condenser system is the very best system for controlling the vapors from tanks because it can handle concentrated gas. It also works with chlorinated hydrocarbons such as perchloroethylene, chloroform, ethylene dichloride, etc. It is just as effective on petroleum hydrocarbons such as gasoline, hexane, benzene, reformate, alcohol, and many other cargoes.

PURGIT site layout

Here is the PURGIT mobile vapor condenser on site degassing a gasoline tank. In the photo you can see the liquid nitrogen tanker, the condenser trailer, the PURGIT truck and an air compressor. There is a detonation arrester on the inlet to the condenser and a turbine meter to accurately measure the volume processed. The hoses go to the storage tank. One hose is the suction hose and the other hose is the return hose.

Hoses to the barge

This photo shows the hoses going to the tank. One hose is for suction, and the other is the return. We modified the tank connection plate and now we can use the manhole for both suction and return connections.

Gasoline tank

Here is one of the 130' diameter tanks we degassed. We did 3 tanks like this one at this tank farm. The floating roof on these tanks was at the low position about 4.5 feet above the floor. The volume of the tank under the floating roof is about 59,700 cubic feet. The gasoline vapor in the tank vapor space was very concentrated. The oxygen was only 17% in the tank when we started.

The job took 7 hours from start to finish and we recovered 275 gallons of gasoline. The gasoline was put in drums and the facility later transfered it back to a storage tank, completing the loop for recycling.

PRUGIT refrigerated condenser

Here is the system in operation. The condenser takes the vapors from the storage tank and chills them until they condense back to liquid. On this job we recovered about 6 drums of gasoline. The amount recovered is dependent on several things:
Amount of time since the tank was taken out of service.
Volume of the tank vapor space.
Temperature of the vapor.
Volatility of the vapor.
Concentration in the tank.



VIDEO of chlorinated solvent job,  2007:
The customer had a chlorinated solvent tank barge that needed to be cleaned. PURGIT was called to do the vapor control. The barge is 195' x 35' and it has 3 cargo tanks.
This is actual footage on site during the vapor control.

Video C shows a 360
o view of a tank barge during a chlorinated solvent degassing operation.
We processed 4 tank volumes on this barge to meet the Texas Commission on Environmental Quality specification. It has about 57,000 cubic feet in each volume. It took less than 6 hours, we used about 8,000 pounds of LN2 and we recovered about 700 liters of chloroform. This shows the recovered liquid container, the condenser and the tank barge.
Same video, different formats: PurgitVideoC.3g2 (3.4 meg) ,  PurgitVideoC.mov (6.3 meg) , PurgitVideoC.avi (7meg) , PurgitVideoC.mpg (11.9 meg)


A vapor condenser can handle chlorinated solvents better than any other control device. Combustion by-products from flares and combustors range from CO and NOx (greenhouse gases) to hazardous by-products which have to be scrubbed. Activated carbon is expensive to operate. Condensers recover the cargo without making hazardous waste.

PURGIT has recovered thousands of gallons of chlorinated solvents and hydrocarbons from our many jobs. Everything we recovered would have been burned or wasted by using activated carbon. Or it might have become an air pollutant. PURGIT is making a real contribution to reducing air pollution.


Ethylene dichloride - chlorinated solvent

PURGIT chlorinated solvent equip

Here is PURGIT equipment set up for vapor control on a tank barge at a shipyard. The suction and return lines are going out to the right. In this photo, we are degassing an ethylene dichloride (EDC) tank barge. We have also controlled perchloroethylene, methylene chloride and trichloroethylene in barges and shore tanks. The condensate is recovered and deposited in containers for recycling.

Condensing is much better for chlorinated solvents because combustor devices make undesirable by-products including acid in the exhaust gas. Combustion devices may have to scrub the exhaust to remove pollutants. Scrubbing makes hazardous waste.

This equipment is excellent for gasoline and hydrocarbons because it can handle the high concentration of the vapor space in those tanks. The condenser can handle 600 or more cubic feet per minute of vapor flow. That is much better than the flow rate of small combustors pulled behind pickup trucks. In fact, the condenser may be 10 times faster than small combustors and perhaps 15 times faster than the IC engine devices.

Tank barge connections

This photo shows the suction and return lines going to the tank barge. By pioneering the closed loop system PURGIT can degas a tank without opening the tank. One advantage of the closed loop system is that we do not suck in air during the vapor control That means that we do not create a flammable condition in the tanks. All combustion devices must suck in air, closed loop condensers do not need to do that. Air in the tank would create a flammable condition in the tanks if there is sufficient VOC gas, and there almost always is, since vapor control would not be necessary otherwise.

This tank barge, like many chemical barges, has a vapor return line system. If the barge did not have a return line, we would run a return line to each tank. On some tanks we have run more than 200' of suction and return line.

22,000 bbl tank barge w/chlorinated solvents

This barge is approx 22,000 bbl capacity total, divided into 6 cargo tanks. It took a little over 12 hours to complete the job on this big barge. We pulled vapors from the liquid line which goes to the bottom of each cargo tank and returned through the vapor system which returns to the top of the tank. Each tank was done one at a time.

For inland barges, the standard barge is called a 'jumbo'. It is 195' x 35' and holds about 10,000 to 11,000 bbl of cargo. The exact amount is dependent on the specific gravity of the cargo. Barges are limited to a draft of 9' (approximately) and so the quantity is driven by the weight of the cargo. These barges usually have 3 cargo tanks, but can have more. They are usually made of carbon steel. Sometimes the tanks are coated with special tank coating to protect the cargo. Very few are made with SS clad plate.

The next larger size barge is in the range of 22,000 bbl. And the largest standard size is in the range of 30,000 bbl.

Collected EDC

Ethylene dichloride condensed in the PURGIT low temperature condenser and transfered to this tote. Approximately 225 gallons of EDC condensate was recovered on this job. Very little water was recovered on this job which indicates that the tanks were padded with nitrogen gas. There wasn't enough water to cover the top of the EDC.

The collected condensate is relatively pure since it is collected from the gas phase in the vapor space of the cargo tank. It appeared to be water-white, clean and pure in the container. The cargo stripped from the tank was off-color, so the recovered cargo was more pure. It could easily be returned to the commercial market.


Methylene chloride - chlorinated solvent

Recovered MEC

June 2007, completed a vapor control project on a 11,000 bbl tank barge last containing methylene chloride. Recovered 4,000 pounds of MEC condensate from the barge tanks in about 6 hours. The condensate filled the totes you see on the left. EDC has a vapor pressure of almost 14 lbs and it is hard to control with activated carbon. It cannot be burned unless the exhaust is scrubbed. By condensing the vapors, the condensate can be recycled. No pollution.

The job took about 6 hours of condenser time.

Clean, water white condensed MEC



Chloroform - chlorinated solvent

Recovered chloroform

June 2007. A tank barge last transported chloroform in the tanks. The barge holds 10,474 bbl capacity. We estimate the concentration in the tanks at about 30% by volume (300,000 ppmv). The job took about 6 hours of condenser time.

Clean, water-white recovered chloroform.



 View case histories:
    Gasoline case at a Houston area tank farm
    Chloroform case at a Houston shipyard  

The PURGIT closed loop vapor condensing system is a big improvement over combustion equipment for many vapor control jobs. There are no flames to get out of control. The blower draws tank vapors through the unit and nitrogen gas is put back in the tank to replace the removed cargo vapors.  Patent pending.

Return to the list of PURGIT jobs.
Return to the main PURGIT page.

Math:
We can degas 130' diameter floating roof tanks in less than a day and meet the Texas Comission on Environmental Quality regulations of 4 volumes.
Here is the math: pi * r² = 13,267 sq ft
13,267 * 4.5' roof height * 4 volumes = 238,806 cu. ft. In Texas the rule says the control device has to process 4 volumes under the floating roof.
238,806 cu ft / 600 cubic feet per minute ( condenser nominal flow rate) = 6.7 hours!
The flow volume is proven by a turbine meter. The proof that the condenser worked is in the loaded drums or totes at the end of the job and temperature reports automatically recorded during the operation.
You benefit by getting your tanks back on line faster. The environment benefits by zero emissions from the condenser.

How long is it going to take to degas your tank? That depends on the amount of cargo left on the floor, the outside temperature, the cargo vapor pressure, the size of the tank, etc. In other words, the time is dependent on the rate of regeneration.

PURGIT is a registered trademark
Copyright 2008