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Hilliard
Emission Controls,
Inc.
3100 Edloe Street Suite 350
Houston, TX 77027
888-621-3132
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Combustion
by-products from flares and combustors range from unburned VOC to CO2,
CO and NOx
(greenhouse gases) to hazardous by-products which have to be
scrubbed. Activated carbon is problematic and expensive to operate. In
comparison, a
vapor condenser can handle chlorinated solvents and hydrocarbons
better than any other control device because it does not make any NOx
or CO. In fact it does not have an exhaust stack. The side benefit is
that it recovers cargo that can be
recycled.
PURGIT has been in the tank vapor control business since 1993. We chose
to develop a refrigerated 'closed loop' system
because of the operational and environmental benefits. It can actually
handle the maximum flow rate when the
tank vapor is concentrated. We claim and can prove 650 scfm from the
1st minute of operation and we do it all the time. Did you know that
the vapor space in a gasoline storage tank may measure 50% by volume
concentration? That is the same that you might find in the gasoline
tank on your car in the summer. That is very rich, so rich it will
not burn without diluting with air. Diluting the tank with air will
create an explosive mixture in the storage tank. PURGIT does not
dilute your tank with air. We are the only company that can process
the rich vapors without adding air. We can process zero air vapors.
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VIDEO
of case history gasoline job, 2007:
The
customer had a gasoline tank that needed to be cleaned. PURGIT was
called to do the vapor control. The tank is 86' diameter x 38' high
and it has a cone roof. The tank has over 1psi of pressure from a
nitrogen pad system. This
is actual footage on site during the vapor control.
Video
A shows the setup at the start of the job. We planned to transfer the
condensate into drums. However we were recovering at the rate of 2
drums per hour and the drums quickly became impractical. This video
starts out showing the condensate in the sight glass, then it pans to
the actual tank we are working on. The video then pans back to the
drums and then to the PURGIT condenser. The next day we changed over
to the frac tank.
Same video, different formats: PurgitVideoA.3g2
(2.8 meg) , PurgitVideoA.mov
(5 meg) , PurgitVideoA.avi
(7.5 meg) , PurgitVideoA.mpg
(9.7 meg)
Video
B shows the condensate as it is transfered to the frac tank. We
finally recovered about 1,200 gallons.
We were recovering so much
condensate that we a manifold to collect from the purgit condenser
pumps. This video shows the manifold and the frac tank and then pans
to the PURGIT condenser. We processed 4 tank volumes, that was about
883,000 cubic feet of vapor. This condensing was completed in about
22 hours, it consumed about 25,000 pounds of liquid nitrogen. The
system recovered about 1,200 gallons of gasoline which was put in the
frac tank. We maintained the pressure on the tank to prevent the tank
from going into a partial pressure condition with the removal of the
gasoline vapor.
Same
video, different formats: PurgitVideoB.3g2
(1.4meg) , PurgitVideoB.mov
(3.2 meg) , PurgitVideoB.avi
(3.8 meg) , PurgitVideoB.mpg
(5 meg)
Gasoline
- VOC cargo
Photographs
taken during the vapor control phase when cleaning a gasoline tank
with a vapor condenser. This refrigerated, low temperature condenser
system is the very best system for
controlling the vapors from tanks because it can handle concentrated
gas. It also works with chlorinated hydrocarbons such as
perchloroethylene, chloroform, ethylene dichloride, etc. It is just
as effective on petroleum hydrocarbons such as gasoline, hexane,
benzene, reformate, alcohol, and many other cargoes.
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Here is the PURGIT mobile vapor condenser on site degassing a gasoline tank. In the photo you can see the liquid nitrogen tanker, the condenser trailer, the PURGIT truck and an air compressor. There is a detonation arrester on the inlet to the condenser and a turbine meter to accurately measure the volume processed. The hoses go to the storage tank. One hose is the suction hose and the other hose is the return hose. |
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This photo shows the hoses going to the tank. One hose is for suction, and the other is the return. We modified the tank connection plate and now we can use the manhole for both suction and return connections. |
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Here
is one of the 130' diameter tanks we degassed. We did 3 tanks like this
one at this tank farm. The floating roof on these tanks was at the low
position about 4.5 feet above the floor. The volume of the tank under
the floating roof is about 59,700 cubic feet. The gasoline vapor in the
tank vapor space was very concentrated. The oxygen was only 17% in the
tank when we started. |
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Here
is the system in operation. The condenser takes the vapors from the
storage tank and chills them until they condense back to liquid. On
this job we recovered about 6 drums of gasoline. The amount recovered
is dependent on several things: |
VIDEO
of chlorinated solvent job, 2007:
The
customer had a chlorinated solvent tank barge that needed to be
cleaned. PURGIT was called to do the vapor control. The barge is 195'
x 35' and it has 3 cargo tanks. This
is actual footage on site during the vapor control.
Video
C shows a 360o
view of a tank barge during a chlorinated solvent degassing
operation.
We processed 4 tank volumes on this barge to meet the
Texas Commission on Environmental Quality specification. It has about
57,000 cubic feet in each volume. It took less than 6 hours, we used
about 8,000 pounds of LN2 and we recovered about 700 liters of
chloroform. This shows the recovered liquid container, the condenser
and the tank barge.
Same video, different formats: PurgitVideoC.3g2
(3.4 meg) , PurgitVideoC.mov
(6.3 meg) , PurgitVideoC.avi
(7meg) , PurgitVideoC.mpg
(11.9 meg)
A
vapor condenser can handle chlorinated solvents better than any other
control device. Combustion by-products from flares and combustors
range from CO and NOx (greenhouse gases) to hazardous by-products
which have to be scrubbed. Activated carbon is expensive to operate.
Condensers recover the cargo without making hazardous waste.
PURGIT
has recovered thousands of gallons of chlorinated solvents and
hydrocarbons from our many jobs. Everything we recovered would have
been burned or wasted by using activated carbon. Or it might have
become an air pollutant. PURGIT is making a real contribution to
reducing air pollution.
Ethylene
dichloride - chlorinated solvent
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Here
is PURGIT equipment set up for vapor control on a tank barge at a
shipyard. The suction and return lines are going out to the right. In
this photo, we are degassing an ethylene dichloride (EDC) tank barge.
We have also controlled perchloroethylene, methylene chloride and
trichloroethylene in barges and shore tanks. The condensate is
recovered and deposited in containers for recycling. |
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This
photo shows the suction and return lines going to the tank barge. By
pioneering the closed loop system PURGIT can degas a tank without
opening the tank. One advantage of the closed loop system is that we do
not suck in air during the vapor control That means that we do not
create a flammable condition in the tanks. All combustion devices must
suck in air, closed loop condensers do not need to do that. Air in the
tank would create a flammable condition in the tanks if there is
sufficient VOC gas, and there almost always is, since vapor control
would not be necessary otherwise. |
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This
barge is approx 22,000 bbl capacity total, divided into 6 cargo tanks.
It took a little over 12 hours to complete the job on this big barge.
We pulled vapors from the liquid line which goes to the bottom of each
cargo tank and returned through the vapor system which returns to the
top of the tank. Each tank was done one at a time. |
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Ethylene
dichloride condensed in the PURGIT low temperature condenser and
transfered to this tote. Approximately 225 gallons of EDC condensate
was recovered on this job. Very little water was recovered on this job
which indicates that the tanks were padded with nitrogen gas. There
wasn't enough water to cover the top of the EDC. |
Methylene chloride - chlorinated solvent
Chloroform - chlorinated solvent
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June
2007. A tank barge last transported chloroform in the tanks. The barge
holds 10,474 bbl capacity. We estimate the concentration in the tanks
at about 30% by volume (300,000 ppmv). The job took about 6 hours of
condenser time. |
View
case histories:
Gasoline case at a Houston area tank farm
Chloroform case at a Houston shipyard
The PURGIT
closed loop vapor condensing system is a big improvement over
combustion equipment for many vapor control jobs. There are no flames
to get out of control. The blower draws tank vapors through the unit
and nitrogen gas is put back in the tank to replace the removed cargo
vapors. Patent pending.
Return
to the list of PURGIT jobs.
Return
to the main PURGIT page.
Math:
We
can degas 130' diameter floating roof tanks in less than a day and
meet the Texas Comission on Environmental Quality regulations of 4
volumes.
Here
is the math: pi * r² = 13,267 sq ft
13,267 * 4.5' roof height
* 4 volumes = 238,806 cu. ft. In Texas the rule says the control
device has to process 4 volumes under the floating roof.
238,806
cu ft / 600 cubic feet per minute ( condenser nominal flow rate) =
6.7 hours!
The flow volume is proven by a turbine meter. The proof
that the condenser worked is in the loaded drums or totes at the end
of the job and temperature reports automatically recorded during the
operation.
You benefit by getting your tanks back on line faster.
The environment benefits by zero emissions from the condenser.
How long is it
going to take to degas your tank? That depends on the amount of cargo
left on the floor, the outside temperature, the cargo vapor pressure,
the size of the tank, etc. In other words, the time is dependent on the
rate of regeneration.
PURGIT is a
registered trademark
Copyright 2008